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Lewis acid-catalyzed regioselective synthesis of chiral alpha-fluoroalkyl amines via asymmetric addition of silyl dienolates to fluorinated sulfinylimines
First author: Liu Yingle
Abstract: A tunable and highly regio- and diastereoselective addition of acyclic silyl dienolates 2 to several alpha-fluoroalkyl sulfinylimines 1 was developed. By appropriate choice of the Lewis acid catalyst, two new chiral alpha-fluoroalkyl amines 3 and 4 were o
Contact the author: Qing Fengling
Page number: 7492-7494
Issue: 68
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PubYear: 2013
Volume: 49
Unit code: 121731
Publication name: Chem. Commun.
The full text link: http://dx.doi.org/10.1039/c3cc43741h
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