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姓 名:
 唐勇
性 别:
 男
职 称:
 研究员
学 历:
 研究生
电 话:
 021-54925156
传 真:
 021-64166128
电子邮件:
 tangy@mail.sioc.ac.cn
个人主页:
 http://tangyong.sioc.ac.cn
通讯地址:
 上海市零陵路345号金属有机国家重点实验室 200032

简历:

学习经历:

1982.09-1986.06 四川师范大学 化学系 本科

1990.09-1993.02 中国科学院上海有机化学研究所 硕士(导师:黄耀曾院士 戴立信院士)

1993.02-1996.02 中国科学院上海有机化学研究所 博士(导师:黄耀曾院士 戴立信院士)

工作经历:

1996.03-1996.07 中国科学院上海有机化学研究所 助理研究员

1996.08-1997.05 美国Colorado State University 博士后

1997.05-1999.04 美国Georgetown University 博士后

1999.05-1999.12 中国科学院上海有机化学研究所 副研究员

2000.01至今中国科学院上海有机化学研究所 研究员

2009.11-2017.01 金属有机化学国家重点实验室 主任

2009.05-2018.12 今中国科学院上海有机化学研究所 副所长

2019.01至今中国科学院上海有机化学研究所 所长


研究方向:

课题组1999年成立,主要从事金属有机化学研究。针对均相催化领域的选择性控制与催化效率等核心科学问题,应用边臂策略设计金属有机催化剂,发展在催化剂的活性中心区域装载配位基团(边臂)以调控其催化行为的新方法和有机合成新反应。
   
主要研究方向:
    1.
不对称催化;
    2.
烯烃聚合催化剂的设计、合成与应用;
    3.
叶立德化学;
    4.
天然产物全合成。


专家类别:
院士

职务:
现任所长、课题组长

社会任职:

获奖及荣誉:

2001年  上海市科技进步一等奖 (自然科学类,第三完成人)

2002年  国家自然科学二等奖 (第三完成人)

2002年  中国科学院-拜尔青年科学家奖

2002年  获国家杰出青年基金

2003年  上海市优秀留学人才

2004年  入选首批新世纪百千万人才工程国家级人选

2004年  SYNTHESIS/SYNLETT期刊奖

2004年  入选上海市优秀学科带头人

2005年  中国科学院优秀研究生指导教师

2006年  中国科学院研究生院优秀教师

2006年  第九届中国青年科技奖

2011年  上海市自然科学一等奖(第一完成人)

2012年  国家自然科学二等奖(第一完成人)

2012年  黄耀曾金属有机化学奖

2014年  庄长恭奖

2015年  上海市科技精英

2015年  入选中国科学院院士

2016年  全国优秀科技工作者

代表论著:

1. Qiong-Jie Liu, Jun Zhu, Xiang-Yang Song, Lijia Wang, Sunewang R. Wang,* and Yong Tang*. Highly enantioselective [3+2] annulation of indoles with quinones to structurally diverse benzofuroindolines. Angew. Chem. Int. Ed. 2018, 57, 3810–3814.

2. Liang-Wen Feng, Hai Ren, Hu Xiong, Pan Wang, Lijia Wang*, Yong Tang*. Reaction of donor-acceptor cyclobutanes with indoles: a general protocol for the formal total synthesis of (±)-strychnine and the total synthesis of (±)-akuammicine. Angew. Chem. Int. Ed. 2017, 56, 3055–3058.

3. Hao Chen, Lijia Wang, Feng Wang, Liu-Peng Zhao, Pan Wang, and Yong Tang*. Access to Hexahydrocarbazoles: The Thorpe–Ingold Effects of the Ligand on Enantioselectivity. Angew. Chem. Int. Ed. 2017, 56, 6942–6945.

4. Jun Zhu, Yu-Jing Cheng, Xiao-Kang Kuang, Lijia Wang, Zhong-Bo Zheng, and Yong Tang*. Highly efficient formal [2+2+2] strategy for the rapid construction of polycyclic spiroindolines: a concise synthesis of 11-demethoxy-16-epi-myrtoidine. Angew. Chem. Int. Ed. 2016, 55, 9224-9228.

5. Qiong-Jie Liu, Lijia Wang, Qi-Kai Kang, X. Peter Zhang*, and Yong Tang*. Cy-SaBOX/copper(II)-catalyzed highly diastereo- and enantioselective synthesis of bicyclic N,O acetals. Angew. Chem. Int. Ed. 2016, 55, 9220-9223.

6. Jiang-Lin Hu, Liang-Wen Feng, Lijia Wang, Zuowei Xie*, Yong Tang*, and Xiaoge Li. Enantioselective construction of cyclobutanes: a new and concise approach to the total synthesis of piperarborenine b. J. Am. Chem. Soc. 2016, 138, 13151-13154.

7. Qi-Kai Kang, Lijia Wang, Qiong-Jie Liu, Jun-Fang Li, Yong Tang*. Asymmetric H2O-nucleophilic ring opening of D–A cyclopropanes: catalyst serves as a source of water. J. Am. Chem. Soc. 2015, 137, 14594-14597.

8. Hao Xu, Jiang-Lin Hu, Lijia Wang, Saihu Liao, Yong Tang*. Asymmetric annulation of donor-acceptor cyclopropanes with dienes. J. Am. Chem. Soc. 2015, 137, 8006-8009.

9. Pan Wang, Liang-Wen Feng, Lijia Wang, Jun-Fang Li, Saihu Liao, Yong Tang*. Asymmetric 1,2-perfluoroalkyl migration: easy access to enantioenriched α-hydroxy-α-perfluoroalkyl esters. J. Am. Chem. Soc. 2015, 137, 4626-4629.

10.Jun Zhu, Yong Liang, Lijia Wang, Zhong-Bo Zheng, K. N. Houk*, Yong Tang*. Remote ester groups switch selectivity: diastereodivergent synthesis of tetracyclic spiroindolines. J. Am. Chem. Soc. 2014, 136, 6900?6903.

11.Saihu Liao, Xiu-Li Sun, Yong Tang*. Sidearm strategy for catalyst design based on bisoxazolines in the remote control of enantioselection and related. Acc. Chem. Res. 2014, 47, 2260.

12.Hu Xiong, Hao Xu, Saihu Liao, Zuowei Xie*, Yong Tang* Copper-Catalyzed Highly Enantioselective Cyclopentannulation of Indoles with Donor–Acceptor Cyclopropanes. J. Am. Chem. Soc., 2013, 135, 7851-7854.

13.Hao Xu, Jian-Ping Qu, Saihu Liao, Hu Xiong, Yong Tang* Highly Enantioselective [3+2] Annulation of Cyclic Enol Silyl Ethers with Donor-Acceptor Cyclopropanes: Accessing 3a-hydroxy [N.3.0]carbobicycles. Angew. Chem. Int. Ed. 2013, 52, 4004-4007.

14.You-Yun Zhou, Jun Li, Lin Ling, Sai-Hu Liao, Xiu-Li Sun,* Yu-Xue Li,* Li-Jia Wang, Yong Tang* Highly Enantioselective [3+3] Cycloaddition of Aromatic Azomethine Imines with Cyclopropanes Directed by p–p Stacking Interactions. Angew. Chem. Int. Ed. 2013, 52, 1452-1456.

15.Chao Deng, Li-Jia Wang, Jun Zhu, Yong Tang* A Chiral Cage-like Copper(I) Catalyst for the Highly Enantioselective Synthesis of 1,1-Cyclopropane Diesters. Angew. Chem. Int. Ed. 2012, 51, 11620-11623.

16.You-Yun Zhou, Li-Jia Wang, Jun Li, Xiu-Li Sun*, Yong Tang* Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and Kinetic Resolution of Donor-Acceptor Cyclopropanes with Amines. J. Am. Chem. Soc. 2012, 134, 9066-9069.

17.Jun Li, Sai-Hu Liao, Hu Xiong, You-Yun Zhou, Xiu-Li Sun*, Yue Zhang, Xiaoguang Zhou, Yong Tang* Highly Diastereo- and Enantioselective Cyclopropanation of 1,2-Disubstituted Alkenes. Angew. Chem. Int. Ed. 2012, 51, 8838-8841.

18.Jiao-Long Zhou, Yong Liang, Chao Deng, Haolai Zhou, Zheng Wang, Xiu-Li Sun, Jun-Cheng Zheng, Zhi-Xiang Yu*, Yong Tang*, Tunable Carbonyl Ylide Reactions: Selective Synthesis of Dihydrofurans and Dihydrobenzoxepines. Angew. Chem. Int. Ed. 2011, 50, 7874–7878.

19.Peng Cao, Chao Deng, You-Yun Zhou, Xiu-Li Sun, Jun-Cheng Zheng, Zuowei Xie, Yong Tang*, Asymmetric Nazarov Reaction Catalyzed by Chiral Tris(oxazoline)/Copper(II). Angew. Chem. Int. Ed. 2010, 49, 4463-4466.

20.Xiao-Hong Yang, Chun-Rong Liu, Cong Wang, Xiu-Li Sun, Yang-Hui Guo, Xin-Ke Wang, Zheng Wang, Zuowei Xie, Yong Tang*, [O-NSR]TiCl3-Catalyzed Copolymerization of Ethylene with Functionalized Olefins. Angew. Chem. Int. Ed. 2009, 48, 8099–8102.

21.Sunewang R. Wang, Chun-Yin Zhu, Xiu-Li Sun, Yong Tang*, Reaction of Allylic Phosphoranes with Iron Porphyrin Carbenoids: Efficient, Selective, and Catalytic Intermolecular Formal Carbenoid Insertion into Olefinic C-H Bonds. J. Am. Chem. Soc. 2009, 131, 4192-4193.

22.Qing-Gang Wang, Xian-Ming Deng, Ben-Hu Zhu, Long-Wu Ye, Xiu-Li Sun, Chuan-Ying Li, Chun-Yin Zhu, Qi Shen, and Yong Tang*, Tandem Michael Addition/Ylide Epoxidation for the Synthesis of Highly Functionalized Cyclohexadiene Epoxide Derivatives. J. Am. Chem. Soc. 2008, 130, 5408-5409.

23.Xiu-Li Sun, Yong Tang*, Ylide-Initiated Michael Addition-Cyclization Reactions beyond Cyclopropanes. Acc. Chem. Res. 2008, 41, 937-948.

24.Long-Wu Ye, Xiu-Li Sun, Qing-Gang Wang, Yong Tang*, Phosphine Catalyzed Intramolecular Formal [3+2] Cycloaddition for the Highly Diastereoselective Synthesis of Bicyclo[n.3.0] Compounds. Angew. Chem., Int. Ed. 2007, 46, 5951-5954.

25.Yan-Biao Kang, Xiu-Li Sun, Yong Tang*, Highly Enantioselective and Diastereoselective Cycloaddition of Cyclopropanes with Nitrones and Its Application in the Kinetic Resolution of 2-Substituted Cyclopropane-1,1-dicarboxylates. Angew. Chem., Int. Ed., 2007, 46, 3918-3921.

26.Chuan-Ying Li, Xiao-Bing Wang, Xiu-Li Sun, Yong Tang*, Jun-Cheng Zheng, Zheng-Hu Xu, Yong-Gui Zhou, Li-Xin Dai, Iron Porphyrin-catalyzed Olefination of Ketenes with Diazoacetate for the Enantioselective Synthesis of Allenes. J. Am. Chem. Soc., 2007, 129, 1494-1495.

27.Xian-Ming Deng, Ping Cai, Song Ye, Xiu-Li Sun, Wei-Wei Liao, Kai Li, Yong Tang*, Yun-Dong Wu*, Li-Xin Dai, Enantioselective Synthesis of Vinylcyclopropanes and Vinylepoxides Mediated by Camphor-Derived Sulfur Ylides: Rationale of Enantioselectivity, Scope, and Limitation. J. Am. Chem. Soc., 2006, 128, 9730-9740.

28.Jun-Cheng Zheng, Wei-Wei Liao, Yong Tang*, Xiu-Li Sun, Li-Xin Dai, The Michael Addition-Elimination of Ylides to a,b-Unsaturated Imines. Highly Stereoselective Synthesis of Vinylcyclopropanecarbaldehydes and Vinylcyclopropylaziridines. J. Am. Chem. Soc., 2005, 127, 12222-12223.

29.Wei-Wei Liao, Kai Li, Yong Tang*, Controllable Diastereoselective Cyclopropanation. Enantioselective Synthesis of Vinylcyclopropanes via Chiral Telluronium Ylides. J. Am. Chem. Soc., 2003, 125, 13030-13031.

30.Song Ye, Zheng-Zheng Huang, Chun-An Xia, Yong Tang*, Li-Xin Dai, A Novel Chiral Sulfonium Yilde: Highly Enantioselective Synthesis of Vinylcyclopropanes. J. Am. Chem. Soc., 2002, 124, 2432-2433.

31.Jian Zhou, Yong Tang*, Side-arm Effect: Improvement of the Enantiomeric Excess in the Asymmetric Michael Addition of Indoles to Alkylidene Malonates J. Am. Chem. Soc., 2002, 124, 9030-9031.

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