1.An efficient and enantioselective approach to the azaspirocyclic core of alkaloids: formal synthesis of halichlorine and pinnaic acid Hong-lu Zhaang, Gang Zhao* and Yu Ding* J. Org. Chem. 2005, 70, 4954.

2. Efficient Allylation of Aldehydes Promoted by Carboxylic Acids Gui-long Li, Gang Zhao* J. Org. Chem. 2005, 70, 4972.

3.Highly effective and recyclable dendritic ligands for the enantioselective aryl transfer reactions to aldehydes

Xin yuan Liu, Xiao yu Wu, Zhuo Chai, Yong yong Wu, Gang Zhao,* and Shi zheng Zhu* J. Org. Chem. 2005, 70, 7432.

4.Stereocontrolled and Convergent Total Synthesis of Amphidinolide T3 Li-Sheng Deng, Xiao-Ping Huang, and Gang Zhao* J. Org. Chem. 2006, 71, 4625.

5.Allylation of aldehydes and imines: promoted by reuseable polymer-supported sulfonamide of N-glycine Gui-long Li and Gang Zhao* Org. Lett. 2006, 8, 633.

6.Highly efficient and reusable dendritic catalysts derived from N-prolylsulfonamide for the asymmetric direct Aldol reaction in water Yongyong Wu, Yazhu Zhang, Menglong Yu, Gang Zhao,* and Shaowu Wang* Org. Lett. 2006, 8, 4417.

7.Synthesis of dendrimer-supported prolinols and their application in enantioselective reduction of ketones Guang-yin Wang, Xin-yuan Liu, Gang Zhao* Synlett 2006, 1150.

8.Synthetic studies toward Amphidinolide H1: segment C14–C26

Lisheng Deng, Zhixiong Ma, Yazhu Zhang, Gang Zhao* Synlett 2007,87.

9.4-Substituted-a, a-diaryl-prolinols improve the enantioselective catalytic epoxidation of enones Yawen Li, Xinyuan Liu, Yingquan Yang, Gang Zhao* J. Org. Chem. 2007, 72, 288.

10.Et₂Zn-catalyzed intramolecular hydroamination of alkynyl sulfonamides and the related tandem cyclization/addition reaction Yan Yin, Wenying Ma, Zhou Chai, Gang Zhao* J. Org. Chem. 2007, 72, 5731.  

11.Tandem Addition\Cyclization Reaction of Organozinc Reagents to 2-Alkynyl Aldehydes: Highly Efficient Regio- and Enantioselective Synthesis of 1, 3-Dihydroisobenzofurans and Tetrasubstituted Furans Zhuo Chai, Zheng-Feng Xie, Xin-Yuan Liu, Gang Zhao* and Ji-De Wang* J. Org. Chem. 2008, 73, 2947.

12. Highly enantioselective tandem cyclopropanation/Wittig reaction of a, b-unsaturated aldehydes with arsonium ylides catalyzed by recyclable dendritic catalyst Yun- Hui Zhao, Chang-Wu Zheng, Gang Zhao*, and Wei- Guo Cao* Tetrahedron: Asymmetry 2008, 19, 701.

13. Highly enantioselective organocatalyzed construction of quaternary carbon centers via cross-aldol reaction of ketones in water Changwu Zheng, Yongyong Wu, Xiaosheng Wang, and Gang Zhao*

Adv. Synth. Catal. 2008, 350, 2690.

14. Organocatalyzed highly enantioselective Michael additions of malonates to enones by using novel primary–secondary diamine catalysts Ying-Quan Yang and Gang Zhao* Chem. Eur. J. 2008, 14, 10888.

15. A convenient route to synthesize N-protected a,a-difluorohomoallylic amines by gem-difluoroallylation of a-amido sulfones ZhensFeng Xie, Zhuo Chai, Gang Zhao,* Ji-De Wang* Synthesis 2008, 3805.

16.Synthesis of indoles via diethylzinc-mediated intramolecular hydroamination reactions of alkynyl sulfonamides YanYin, Zhuo Chai, Wen-Ying Ma, Gang Zhao* Synthesis 2008, 4036.

17. Synthetic studies toward the total synthesis of Amphidinolide H1 Litsheng Deng, Zhixiong Ma, Gang Zhao* Synlett 2008, 728.

18.Synthesis of 3-fluoro-2,5-disubstituted furans and further derivative reactions to access fluorine-containing 3,3’- bifurans and tetrasubstituted furans Peng Li, Zhuo Chai, Gang Zhao* and Shi-Zheng Zhu*Synlett 2008, 2547.

19. Enantioselective synthesis of naphthopyran derivatives catalyzed by bifunctional thiourea-tertiary amines

Xiaosheng Wang, Gaosheng Yang,* and Gang Zhao* Tetrahedron: Asymmetry 2008, 19, 709.

20. An unexpected tandem enantioselective Michael addition/oxa-nucleophilic rearrangement reaction of b,g-unsaturated a-keto esters catalyzed by cinchona alkaloids Hai-Feng Wang, Chang-Wu Zheng, Ying-Quan Yang, Zhuo Chai, Gang Zhao* Tetrahedron: Asymmetry 2008, 19, 2608.