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姓 名:
 郭勇
性 别:
 男
职 称:
 副研究员
学 历:
 博士研究生
电 话:
 021-54925462
传 真:
 
电子邮件:
 yguo@sioc.ac.cn
个人主页:
 
通讯地址:
 上海市零陵路345号 200032

简历:
2001年中国科学院上海有机化学所博士学位,导师陈庆云院士。先后在日本冈山大学,冈山理科大学和美国爱达荷大学留学,导师为Kenji Uneyama (宇根山健治)教授,Shun-Ichi Murahashi (村桥俊一)教授和 Jean’ne M. Shreeve教授。2010年4月作为海外人才引进回国开展研究工作。曾经参与研究过的课题为:1)二氟二碘甲烷和其衍生物的反应研究;2)镁促进的三氟甲基的选择性脱氟和具有生理和药理活性的含氟氨基酸和多肽的合成;3)低价金属对三氟甲基邻位碳氢键的活化和后续反应;4)高能材料富氮盐的合成以及性质的理论预测 5)钯催化的含氟烯醇硅醚的芳基化反应。

研究方向:
(1)有机氟化学反应研究,从源头上为材料科学建立合成方法学,着重于开发一些新反应,以达到提高反应效率,节约能源,和减少对环境的影响的目的,并且利用氟原子的特殊性合成一些具有生理活性的化合物,即将展开含氟烯醇手性烯丙基化反应和含氟化合物的C-H键活化两个方向的工作; (2)有机氟化物的合成及其在材料领域中的应用,其中包括含氟的光伏材料和高能材料等,比如说含氟卟啉,含氟多氮化合物等; (3)具有特殊功能的有机材料的开发,注重于能源方面,尤其是有机小分子; (4)用于电子产业的高纯试剂的开发,如高纯氢氟酸;(5) 多品种的含氟聚合物的开发,从不同纯度和品级的含氟单体出发合成具有不同分子量分布的聚四氟乙烯和聚偏二氟乙烯等,并对含氟聚合物进行改性研究。

专家类别:
副研究员

职务:
课题组长

社会任职:

获奖及荣誉:
代表论著:
1.Guo, Y.; Tao, G.-H.; Blumenfeld, A.; Shreeve, J. M. “Impact of Silyl Enol Ether Stability on Palladium-catalyzed Arylations,” Organometallics, 2010, 29, 1818-1823.
2.Guo, Y.; Tao, G.-H.; Zeng, Z.; Gao, H.; Shreeve, J. M.  “Energetic Salts Based on Monoanions of N,N-bis[1H-Tetrazol-5-yl]amine and 5,5’-Bis(tetrazole),” Chemistry -  A European Journal, 2010, 16, 3753-3762.
3.Tao, G.-H.; Guo, Y.; Parrish, D. A.; Shreeve, J. M. “Energetic 1,5-Diamino-4H-tetrazolium Nitro-substituted Azolates,” Jounral of Materials Chemistry, 2010, 20,  2999-3005
4.Zhang, Y.; Gao, H.; Guo, Y.; Joo, Y.-H.; Shreeve, J. M. “Hypergolic N,N-Dimethylhydrozimiun Ionic Liquids,” Chemistry – A European Journal, 2010, 16, 3114-3120.
5.Guo, Y.; Tao, G.-H., Joo, Y.-H., Wang, R.; Twanley, B.; Parrish, D. A.; Shreeve, J. M. “Impact Insensitive Dianionic Dinitrourea Salts: The CN4O52- Anion Paired with Nitrogen-Rich Cations,” Energy&Fuels, 2009, 23, 4567−4574.
6.Guo, Y.; Zhao X.; Zhang, D.; Murahashi, S.−I. “Iridium−Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes: A Csp3−H Bond Activation a-to the Trifluoromethyl Group,” Angewandte Chemie, 2009, 121, 2081-2083; Angewandte Chemie Internation Edition, 2009, 48, 2047−2049.
7.Guo, Y.; Twamley, B.; Shreeve J. M. “Pd−Catalyzed Arylation of Silyl Enol Ethers of Substituted a−Fluoroketones,” Organic & Biomolecular Chemistry, 2009, 1716−1722.
8.Zeng, Z.; Guo, Y. Twamley, B.; Shreeve, J. M. “Energetic Polyazole Polynitrobenzenes and Their Coordination Complexes,” Chemical Communications, 2009, 6014−6016.
9.Wang, R.; Guo, Y.; Zeng, Z.; Shreeve, J. M. “Nitrogen−rich Nitroguanidine-functionalized Tetrazolate Energetic Salts,” Chemical Communications, 2009, 2697-2699.
10.Wang, R.; Guo, Y.; Zeng, Z.; Parrish, D. A.; Twamley, B.; Shreeve, J. M. “Furazan−functionalized Tetrazolate−based Salts: A New Family of Insensitive Energetic Materials,” Chemistry – A European Journal, 2009, 15, 2625−2634.
11.Tao, G.−H.; Guo, Y.; Joo, Y.−H; Twamley, B.; Shreeve J. M. “Energetic Nitrogen−rich Salts and Ionic Liquids: 5−Aminotetrazole (AT) as a Weak Acid,” Journal of Materials Chemistry, 2008, 18, 5524–5530.
12.Guo, Y.; Fujiwara, K.; Amii, H.; Uneyama, K. “Selective Defluorination Approach to N−Cbz−3,3−difluoro−2−difluoromethylenepyrrole and its Application to 3,3−Difluoroproline Dipeptide Synthesis,” Journal of Organic Chemistry, 2007, 72, 8523­−8526.
13.Guo, Y.; Shreeve, J. M. “Effect of Fluorine on Palladium­−catalyzed Cross−coupling Reactions of Aryl Bromides with Trifluoromethyl Aryl Ketones via Difluoroenol Silyl or Monofluoroenol Silyl Ethers,” Chemical Communications, 2007, 3583−3585.
14.Guo, Y.; Gao, H.; Twamley, B.; Shreeve, J. M. “Energetic Nitrogen Rich Salts of N, N−bis[1(2)H−tetrazol−5−yl]amine,” Advanced Materials, 2007, 19, 2884−2888.
15.Guo, Y.; Shreeve, J. M. “Difluoromethylene Compounds as Precursors to Ketones, Carboxylic Acids, Esters, Amides and Carbonates,” Journal of Fluorine Chemistry, 2007, 128, 1280−1285.
16.Guo, Y.; Fujiwara, K.; Uneyama, K. “A Novel Route to Dipeptides via Noncondensation of Amino Acids: 2−Aminoperfluoropropene as a Synthon for Trifluoroalanine Dipeptides,” Organic Letters, 2006, 8, 827−829.
17.Xiao, J.−C.; Duan, J.−X.; Li, A.−R.; Guo, Y.; Chen Q.−Y. “A Simple Method for Preparing Difluorodiodomethane from Difluoro(fluorosulfonyl)acetyl Fluoride,” Collection of Czechoslovak Chemical Communications, 2002, 67, 1320−1324.
18.Guo, Y.; Chen, Q.−Y. “Iododifluoromethyl Alkenes [ICF2CH=CHR]: a Labile System Generated from 1,1−Difluoro−1,3−Diiodoalkanes and its Trapping with Nucleophiles,” Journal of Fluorine Chemistry, 2001, 107, 89−96.
19.Guo, Y.; Chen. Q.-Y “The Reaction and its Product Conversion of Diflourodiiodomethane with Ethyl Vinyl Ether,” 《化学学报》, 2001, 59, 1722-1729.
20.Guo, Y.; Chen. Q.-Y “The Electron Transfer Reactions of 1,3-Diiodohexafluoropropane,” 《化学学报》, 2001, 59, 1730-1734.
21.Guo, Y.; Chen, Q.−Y. “The Reactions of Difluorodiiodomethane with Nucleophiles,” Journal of Fluorine Chemistry, 2000, 102, 105−109.
书籍章节
22.Uneyama, K.; Guo, Y.; Fujiwara, K.; Komatsu, Y. “A Novel Strategy for the Synthesis of Trifluoroalanine Oligopeptides,” Current Fluoroorganic Chemistry, 2007, ACS Symposium Series 949, Chapter 29, 462-476.
国际会议
23.Guo, Y.; Fujiwara, K.; Amii, H.; Uneyama, K. “Selective Defluorination Approach to the Synthesis of b,b−Difluoroproline−containing Dipeptides,” 17th International Symposium on Fluorine Chemistry, Shanghai, China, poster, 2005.
24.Guo, Y.; Amii, H.; Uneyama, K. “The Selective Defluorination of Bis(trifluromethyl)imines and its Derivatives,” International Conference on Fluorine Chemistry ’04 Kyoto, Japan, poster, 2004.
25.  Guo, Y.; Amii, H.; Uneyama, K. “The Selective Defluorination of Bis(trifluromethyl)imines,” The Ninth International Kyoto Conference on New Aspects of Organic Chemistry, Japan, poster, 2003.
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