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姓 名:
 赵延川
性 别:
 男
职 称:
 研究员
学 历:
 博士研究生
电 话:
 021-54925545
传 真:
 021-64166128
电子邮件:
 zhaoyanchuan@sioc.ac.cn
个人主页:
 http://zhaoyanchuan.fluorinelab.ac.cn
通讯地址:
 上海市徐汇区零陵路345号 200032

简历:

  2003.09 – 2007.07      吉林大学,学士 

  2007.09 – 2012.07      中国科学院上海有机化学研究所,博士 (导师:胡金波研究员) 

  2012.07 – 2013.03      中国科学院上海有机化学研究所,研究助理  

  2015.04 – 2015.05      美国伊利诺伊香槟分校,访问学者 (导师: Prof. Jeffrey S. Moore)         

  2013.03 – 2017.02      美国麻省理工学院,博士后 (导师: Prof. Timothy M. Swager)         


研究方向:
  1. 基于核磁共振及仲氢诱导核极化的化学传感检测方法
  2. 机械化学及固相有机合成
  3. 功能性含氟及多孔材料

专家类别:
研究员

职务:
课题组长

社会任职:

获奖及荣誉:

  2012 年 上海市优秀毕业生   

  2012 年 中国科学院院长优秀奖 

代表论著:

1. Xu, Z.; Liu, C.; Zhao, S.; Chen, S.; Zhao, Y. Molecular Sensors for NMR-Based Detection. Chem. Rev. 2018, acs.chemrev.8b00202. Invited
2. Zhao, Y.; He, Y.; Swager, T. M. Porous Organic Polymers via Ring Opening Metathesis Polymerization. ACS Macro Lett. 2018, 7, 300–304.
3. Zhao, Y.; Rocha, S. V.; Swager, T. M. Mechanochemical Synthesis of Extended Iptycenes. J. Am. Chem. Soc. 2016, 138, 13834-13837.
4. Zhao, Y.; Chen, L.; Swager, T. M. Simultaneous Identification of Neutral and Anionic Species in Complex Mixtures without Separation. Angew. Chem., Int. Ed. 2016, 55, 917-921.
5. Zhao, Y.; Jiang, F.; Hu, J. Spontaneous Resolution of Julia-Kocienski Intermediates Facilitates Phase Separation to Produce Z- and E-Monofluoroalkenes. J. Am. Chem. Soc. 2015, 137. 5199-5203. Highlighted in JACS Spotlights and Chem-Station
6. Zhao, Y.; Swager, T. M. Simultaneous Chirality Sensing of Multiple Amines by 19F NMR. J. Am. Chem. Soc. 2015, 137, 3221-3224. Highlighted in C&E News, JACS Spotlights, Chemistry Views, and Chem-Station
7. Zhao, Y.; Markopoulos, G.; Swager, T. M. 19F NMR Fingerprints: Identification of Neutral Organic Compounds in a Molecular Container. J. Am. Chem. Soc. 2014, 136, 10683-10690. Highlighted in “In the Pipeline”
8. Zhao, Y.; Swager, T. M. Detection and Differentiation of Neutral Organic Compound by 19F NMR with a Tungsten Calix[4]arene Imido Complex. J. Am. Chem. Soc. 2013, 135, 18770-18773.
9. Zhao, Y.; Ni, C.; Jiang, F.; Gao, B.; Shen, X.; Hu, J. Copper-Catalyzed Debenzoylative Monofluoromethylation of Aryl Iodides Assisted by the Removable (2-Pyridyl)sulfonyl Group. ACS Catal. 2013, 3, 631-634.
10. Zhao, Y.; Gao, B.; Ni, C.; Hu, J. Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group. Org. Lett. 2012, 14, 6080-6083. Highlighted in Synfacts
11. Zhao, Y.; Bing, G.; Hu, J. From Olefination to Alkylation: In-Situ Halogenation of Julia-Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and bromodifluoromethylation of Carbonyl Compounds. J. Am. Chem. Soc. 2012, 134, 5790-5793.
12. Zhao, Y.; Hu, J., Palladium-Catalyzed 2,2,2-Trifluoroethylation of Organoboronic Acids and Esters. Angew. Chem., Int. Ed. 2012, 51, 1033-1036.
13. Zhao, Y.; Huang, W.; Zheng, J.; Hu, J., Efficient and Direct Nucleophilic Difluoromethylation of Carbonyl Compounds and Imines with Me3SiCF2H at Ambient or Low Temperature. Org. Lett. 2011, 13, 5342-5345. Highlighted in Synfacts Me3SiCF2H is now commercially available at Sigma-Aldrich http://www.sigmaaldrich.com/catalog/papers/21910464
14. Zhao, Y.; Huang, W.; Zhu, L.; Hu, J., Difluoromethyl 2-Pyridyl Sulfone: A New gem-Difluoroolefination Reagent for Aldehydes and Ketones. Org. Lett. 2010, 12, 1444-1447. Difluoromethyl 2-Pyridyl Sulfone is now commercially available at Sigma-Aldrich http://www.sigmaaldrich.com/catalog/papers/20210302

 

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