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姓 名: |
刘国生 |
性 别: |
男 |
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职 称: |
研究员 |
学 历: |
研究生 |
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电 话: |
021-54925346 |
传 真: |
021-64166128 |
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电子邮件: |
gliu@mail.sioc.ac.cn |
个人主页: |
http://guoshengliu.sioc.ac.cn |
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通讯地址: |
上海市零陵路345号 200032 |
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| 简历： |
1991,9-1995,7南京理工大学化工学院，获工学学士；
1996,9-1999,8中科院大连化学物理研究所，获理学硕士；
1999,9-2002,8中科院上海有机化学研究所，获理学博士；
2003,3-2005,7美国Lehigh大学，博士后；
2005,8-2007,7美国威斯康辛大学麦迪逊分校化学系,研究助理；
2007,7-中科院上海有机所研究员。 |
| 研究方向： |
| 本课题组的研究集中在有机化学，金属催化和材料化学的前沿交叉区域，主要基于C-M键的基元反应，通过设计和合成一些新型的金属催化剂来实现有机分子的高选择性转化，并对反应机理的进行研究，从而能够更多的了解这些金属催化的反应，对金属的基元反应更多的认识。 |
| 代表论著： |
- Wu, Liang; Qiu, Shuifa; Liu, Guosheng,* “Br？nsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes:Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation.” Org. Lett. 2009, 11, 2707.
- Qiu, Shuifa; Wei, Yunyang; Liu, Guosheng;* “Palladium-Catalyzed Intramolecular Hydro- amination of Allenes Coupled to Aerobic Alcohol Oxidation.” Chem. Eur. J. 2009, 15, 2751.
- Liu, Guosheng;* Yin, Guoyin; Wu, Liang; “Palladium-catalyzed intermolecular aerobic oxidative amination of terminal alkenes: effic- ient synthesis of linear allylamine derivatives.” Angew. Chem. Int. Ed. 2008, 47, 4733.
- Yin, Guoyin; Liu, Guosheng;* “Palladium-catalyzed oxidative cyclization of enyne with hydrogen peroxide as the oxidant.” Angew. Chem. Int. Ed. 2008, 47, 5442.
- Chai, Jianfang; Liu, Guosheng; Chaicharoen, Kittisak; Wesdemiotis, Chrys; Jia, Li;* Macromolecules 2008, 41, 8980.
- Liu, Guosheng; Stahl, Shannon. S;* “Two-Faced Reactivity of Alkenes: cis- versus trans-aminopalladation in Aerobic Pd-Catalyzed Intramolecular Aza-Wacker Reactions.” J. Am. Chem. Soc. 2007, 129, 6328-6335.
- Liu, Guosheng; Stahl, Shannon. S;* “Highly Regeioselective Pd-Catalyzed Intermolecular Aminoacetoxylation of Alkene and Evidence for the cis-Aminopalladation and SN2 C-O Bond Formation”, J. Am. Chem. Soc. 2006, 128， 7179-7181.
- Liu, Guosheng; Jia, Li;* “Cobalt-Catalyzed Carbonylative Copolymerizaiton of N-Alkylazetidines and Tetrahydrofuran”, Angw. Chem. Int. Ed. 2006, 45, 129.
- Liu, Guosheng; Jia, Li;* “Design of Catalytic Carbonylative Polymerizations of Heterocylces. Synthesis of Polyesters and Amphiphilic Poly(amide-block-ester)s”, J. Am. Chem. Soc. 2004, 126, 14716.
- Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Coupling of Allenoic Acids and a,b-Unsaturated Carbonyl Compounds through Tandem Intramolecular oxypalladation and Conjugate Addition Reactions”, Tetrahedron Lett. 2003, 44, 127.
- Lei, Aiwen; Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Highly Regio- and Diastereoselective Cyclization of Difunctional Allylic N-Tosylcarbamates. A Convenient Synthesis of Optically Active 4-Vinyl-2-oxazolidinones and Total Synthesis of 1,4-Dideoxy-1,4-imino- L-xylitol”, J. Org. Chem. 2002, 67, 974.
- Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Coupling Reactions of Intramolecular Carbopalladation of Alkyne with Allylic Compounds”, Tetrahedron Lett. 2002, 43, 6791.
- Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Tandem Reaction of Intramolecular Aminopalladation of Allenyl N-Tosylcarbamates and Conjugate Addition”, Org. Lett. 2001, 3, 3879.
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